Vernier structures of metal benzenedicarboxylats MIL-47 and MIL-53

Evaluation of the Metal-Organic Frameworks MIL-47, MIL-53 and Cu3(BTC)2 for the Adsorptive Separation of Molecular Mixtures

A new class of microporous adsorbents, the metal-organic frameworks was recently developed. Despite their promising characteristics, not much is known about their adsorption behaviour, certainly for mixtures. In this work, vapour and gas phase adsorption and separation of (i) linear and branched alkanes, cyclohexane and benzene, (ii) C8 alkylaromatic compounds and (iii) CO2 and CH4 is studied o...

Synthesis of Nanoporous Metal Organic Framework MIL-53-Cu and Its Application for Gas Separation

MIL-53-Cu has been synthesized hydrothermally and has been used for the first time for gas separation. MIL-53-Cu shows adsorption capacities of 8.1, 0.7 and 0.5 m.mol/g, respectively, for CH4, CO2 and H2 at 30 bar and 298 K. The high CH4 adsorption capacity of MIL-53-Cu maybe attributed to the high pore volume and large number of open metal sites....

The cc., c.cm., MIL., mil., and ml.

The cc., c.cm., MIL., mil., and ml.

[This corrects the article on p. 281 in vol. 83.].

synthesis of nanoporous metal organic framework mil-53-cu and its application for gas separation

mil-53-cu has been synthesized hydrothermally and has been used for the first time for gas separation. mil-53-cu shows adsorption capacities of 8.1, 0.7 and 0.5 m.mol/g, respectively, for ch4, co2 and h2 at 30 bar and 298 k. the high ch4 adsorption capacity of mil-53-cu maybe attributed to the high pore volume and large number of open metal sites. the high selectivity for ch4 over co2 (11.5) an...